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    Saykally, Richard

    TitleChemist Senior Faculty SE
    SchoolLawrence Berkeley National Lab
    DepartmentChemical Sciences
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/642-8269
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Lam RK, Shih O, Smith JW, Sheardy AT, Rizzuto AM, Prendergast D, Saykally R. Erratum: "Electrokinetic detection for x-ray spectra of weakly interacting liquids: n-decane and n-nonane" [J. Chem. Phys. 140, 234202 (2014)]. J Chem Phys. 2017 Jun 28; 146(24):249902. PMID: 28668025.
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      2. Cole WT, Fellers RS, Viant MR, Saykally R. Hydrogen bond breaking dynamics in the water pentamer: Terahertz VRT spectroscopy of a 20 µm libration. J Chem Phys. 2017 Jan 07; 146(1):014306. PMID: 28063427.
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      3. Rizzuto AM, Irgen-Gioro S, Eftekhari-Bafrooei A, Saykally R. Broadband Deep UV Spectra of Interfacial Aqueous Iodide. J Phys Chem Lett. 2016 Oct 6; 7(19):3882-3885. PMID: 27635463.
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      4. Cole WT, Farrell JD, Wales DJ, Saykally R. Structure and torsional dynamics of the water octamer from THz laser spectroscopy near 215 µm. Science. 2016 Jun 3; 352(6290):1194-7. PMID: 27257252.
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      5. Lam RK, Smith JW, Saykally R. Communication: Hydrogen bonding interactions in water-alcohol mixtures from X-ray absorption spectroscopy. J Chem Phys. 2016 May 21; 144(19):191103. PMID: 27208929.
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      6. Cole WT, Fellers RS, Viant MR, Leforestier C, Saykally R. Far-infrared VRT spectroscopy of the water dimer: Characterization of the 20 µm out-of-plane librational vibration. J Chem Phys. 2015 Oct 21; 143(15):154306. PMID: 26493906.
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      7. Smith JW, Lam RK, Shih O, Rizzuto AM, Prendergast D, Saykally R. Properties of aqueous nitrate and nitrite from x-ray absorption spectroscopy. J Chem Phys. 2015 Aug 28; 143(8):084503. PMID: 26328852.
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      8. Smith JW, Lam RK, Sheardy AT, Shih O, Rizzuto AM, Borodin O, Harris SJ, Prendergast D, Saykally R. X-Ray absorption spectroscopy of LiBF4 in propylene carbonate: a model lithium ion battery electrolyte. Phys Chem Chem Phys. 2014 Nov 21; 16(43):23568-75. PMID: 25175723.
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      9. Lam RK, Shih O, Smith JW, Sheardy AT, Rizzuto AM, Prendergast D, Saykally R. Electrokinetic detection for X-ray spectra of weakly interacting liquids: n-decane and n-nonane. J Chem Phys. 2014 Jun 21; 140(23):234202. PMID: 24952534.
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      10. Shih O, England AH, Dallinger GC, Smith JW, Duffey KC, Cohen RC, Prendergast D, Saykally R. Cation-cation contact pairing in water: guanidinium. J Chem Phys. 2013 Jul 21; 139(3):035104. PMID: 23883058.
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      11. Duffey KC, Shih O, Wong NL, Drisdell WS, Saykally R, Cohen RC. Evaporation kinetics of aqueous acetic acid droplets: effects of soluble organic aerosol components on the mechanism of water evaporation. Phys Chem Chem Phys. 2013 Jul 28; 15(28):11634-9. PMID: 23677455.
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      12. Saykally R. Air/water interface: Two sides of the acid-base story. Nat Chem. 2013 Feb; 5(2):82-4. PMID: 23344441.
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      13. Richardson JO, Wales DJ, Althorpe SC, McLaughlin RP, Viant MR, Shih O, Saykally R. Investigation of terahertz vibration-rotation tunneling spectra for the water octamer. J Phys Chem A. 2013 Aug 15; 117(32):6960-6. PMID: 23286830.
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      14. Saykally R, Wales DJ. Chemistry. Pinning down the water hexamer. Science. 2012 May 18; 336(6083):814-5. PMID: 22605742.
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      15. Otten DE, Shaffer PR, Geissler PL, Saykally R. Elucidating the mechanism of selective ion adsorption to the liquid water surface. Proc Natl Acad Sci U S A. 2012 Jan 17; 109(3):701-5. PMID: 22233805.
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      16. Duffin AM, England AH, Schwartz CP, Uejio JS, Dallinger GC, Shih O, Prendergast D, Saykally R. Electronic structure of aqueous borohydride: a potential hydrogen storage medium. Phys Chem Chem Phys. 2011 Oct 14; 13(38):17077-83. PMID: 21822506.
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      17. Duffin AM, Schwartz CP, England AH, Uejio JS, Prendergast D, Saykally R. pH-dependent x-ray absorption spectra of aqueous boron oxides. J Chem Phys. 2011 Apr 21; 134(15):154503. PMID: 21513391.
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      18. Miller AE, Petersen PB, Hollars CW, Saykally R, Heyda J, Jungwirth P. Behavior of ß-amyloid 1-16 at the air-water interface at varying pH by nonlinear spectroscopy and molecular dynamics simulations. J Phys Chem A. 2011 Jun 16; 115(23):5873-80. PMID: 21413795.
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      19. Saykally R, Michael EA, Wang J, Greene CH. Recombination-pumped triatomic hydrogen infrared lasers. J Chem Phys. 2010 Dec 21; 133(23):234302. PMID: 21186866.
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      20. Schwartz CP, Fatehi S, Saykally R, Prendergast D. Importance of electronic relaxation for inter-coulombic decay in aqueous systems. Phys Rev Lett. 2010 Nov 5; 105(19):198102. PMID: 21231199.
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      21. Kelly DN, Schwartz CP, Uejio JS, Duffin AM, England AH, Saykally R. Communication: Near edge x-ray absorption fine structure spectroscopy of aqueous adenosine triphosphate at the carbon and nitrogen K-edges. J Chem Phys. 2010 Sep 14; 133(10):101103. PMID: 20849154.
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      22. Schwartz CP, Saykally R, Prendergast D. An analysis of the NEXAFS spectra of a molecular crystal: alpha-glycine. J Chem Phys. 2010 Jul 28; 133(4):044507. PMID: 20687663.
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      23. Schwartz CP, Uejio JS, Duffin AM, England AH, Kelly DN, Prendergast D, Saykally R. Investigation of protein conformation and interactions with salts via X-ray absorption spectroscopy. Proc Natl Acad Sci U S A. 2010 Aug 10; 107(32):14008-13. PMID: 20660784.
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      24. Uejio JS, Schwartz CP, Duffin AM, England A, Prendergast D, Saykally R. Monopeptide versus monopeptoid: insights on structure and hydration of aqueous alanine and sarcosine via X-ray absorption spectroscopy. J Phys Chem B. 2010 Apr 8; 114(13):4702-9. PMID: 20235589.
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      25. Fatehi S, Schwartz CP, Saykally R, Prendergast D. Nuclear quantum effects in the structure and lineshapes of the N2 near-edge x-ray absorption fine structure spectrum. J Chem Phys. 2010 Mar 7; 132(9):094302. PMID: 20210393.
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      26. Drisdell WS, Saykally R, Cohen RC. On the evaporation of ammonium sulfate solution. Proc Natl Acad Sci U S A. 2009 Nov 10; 106(45):18897-901. PMID: 19861551.
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      27. Bush MF, O'Brien JT, Prell JS, Wu CC, Saykally R, Williams ER. Hydration of alkaline earth metal dications: effects of metal ion size determined using infrared action spectroscopy. J Am Chem Soc. 2009 Sep 23; 131(37):13270-7. PMID: 19754186.
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      28. Schwartz CP, Uejio JS, Duffin AM, England AH, Prendergast D, Saykally R. Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy. J Chem Phys. 2009 Sep 21; 131(11):114509. PMID: 19778131.
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      29. Onorato RM, Otten DE, Saykally R. Adsorption of thiocyanate ions to the dodecanol/water interface characterized by UV second harmonic generation. Proc Natl Acad Sci U S A. 2009 Sep 8; 106(36):15176-80. PMID: 19706409.
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      30. Schwartz CP, Uejio JS, Saykally R, Prendergast D. On the importance of nuclear quantum motions in near edge x-ray absorption fine structure spectroscopy of molecules. J Chem Phys. 2009 May 14; 130(18):184109. PMID: 19449910.
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      31. Bush MF, Saykally R, Williams ER. Infrared action spectra of Ca2+(H2O)(11-69) exhibit spectral signatures for condensed-phase structures with increasing cluster size. J Am Chem Soc. 2008 Nov 19; 130(46):15482-9. PMID: 18939831.
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      32. Bush MF, Oomens J, Saykally R, Williams ER. Alkali metal ion binding to glutamine and glutamine derivatives investigated by infrared action spectroscopy and theory. J Phys Chem A. 2008 Sep 18; 112(37):8578-84. PMID: 18714968.
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      33. Bush MF, Saykally R, Williams ER. Reactivity and infrared spectroscopy of gaseous hydrated trivalent metal ions. J Am Chem Soc. 2008 Jul 16; 130(28):9122-8. PMID: 18558673.
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      34. Uejio JS, Schwartz CP, Duffin AM, Drisdell WS, Cohen RC, Saykally R. Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets. Proc Natl Acad Sci U S A. 2008 May 13; 105(19):6809-12. PMID: 18463292.
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      35. Bush MF, Oomens J, Saykally R, Williams ER. Effects of alkaline earth metal ion complexation on amino acid zwitterion stability: results from infrared action spectroscopy. J Am Chem Soc. 2008 May 21; 130(20):6463-71. PMID: 18444620.
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      36. Cappa CD, Smith JD, Wilson KR, Saykally R. Revisiting the total ion yield x-ray absorption spectra of liquid water microjets. J Phys Condens Matter. 2008 May 21; 20(20):205105. PMID: 21694286.
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      37. Lin W, Han JX, Takahashi LK, Harker HA, Keutsch FN, Saykally R. Terahertz vibration-rotation-tunneling spectroscopy of the water tetramer-d8: combined analysis of vibrational bands at 4.1 and 2.0 THz. J Chem Phys. 2008 Mar 7; 128(9):094302. PMID: 18331088.
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      38. Smith JD, Saykally R, Geissler PL. The effects of dissolved halide anions on hydrogen bonding in liquid water. J Am Chem Soc. 2007 Nov 14; 129(45):13847-56. PMID: 17958418.
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      39. Bush MF, Saykally R, Williams ER. Hydration of the calcium dication: direct evidence for second shell formation from infrared spectroscopy. Chemphyschem. 2007 Oct 22; 8(15):2245-53. PMID: 17876863.
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      40. Bush MF, Prell JS, Saykally R, Williams ER. One water molecule stabilizes the cationized arginine zwitterion. J Am Chem Soc. 2007 Nov 7; 129(44):13544-53. PMID: 17929811.
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      41. Onorato RM, Muraki N, Knutsen KP, Saykally R. Chirped coherent anti-Stokes Raman scattering as a high-spectral- and spatial-resolution microscopy. Opt Lett. 2007 Oct 1; 32(19):2858-60. PMID: 17909597.
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      42. Lin W, Han JX, Takahashi LK, Loeser JG, Saykally R. Terahertz vibration-rotation-tunneling spectroscopy of the ammonia dimer. II. A-E states of an out-of-plane vibration and an in-plane vibration. J Phys Chem A. 2007 Oct 4; 111(39):9680-7. PMID: 17824592.
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      43. Bush MF, Forbes MW, Jockusch RA, Oomens J, Polfer NC, Saykally R, Williams ER. Infrared spectroscopy of cationized lysine and epsilon-N-methyllysine in the gas phase: effects of alkali-metal ion size and proton affinity on zwitterion stability. J Phys Chem A. 2007 Aug 16; 111(32):7753-60. PMID: 17636967.
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      44. Nakayama Y, Pauzauskie PJ, Radenovic A, Onorato RM, Saykally R, Liphardt J, Yang P. Tunable nanowire nonlinear optical probe. Nature. 2007 Jun 28; 447(7148):1098-101. PMID: 17597756.
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      45. Cappa CD, Smith JD, Messer BM, Cohen RC, Saykally R. Nature of the aqueous hydroxide ion probed by X-ray absorption spectroscopy. J Phys Chem A. 2007 Jun 7; 111(22):4776-85. PMID: 17439200.
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      46. Bush MF, Saykally R, Williams ER. Evidence for water rings in the hexahydrated sulfate dianion from IR spectroscopy. J Am Chem Soc. 2007 Feb 28; 129(8):2220-1. PMID: 17266315.
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      47. Bush MF, O'Brien JT, Prell JS, Saykally R, Williams ER. Infrared spectroscopy of cationized arginine in the gas phase: direct evidence for the transition from nonzwitterionic to zwitterionic structure. J Am Chem Soc. 2007 Feb 14; 129(6):1612-22. PMID: 17249666.
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      48. Smith JD, Cappa CD, Messer BM, Drisdell WS, Cohen RC, Saykally R. Probing the local structure of liquid water by X-ray absorption spectroscopy. J Phys Chem B. 2006 Oct 12; 110(40):20038-45. PMID: 17020392.
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      49. Smith JD, Cappa CD, Drisdell WS, Cohen RC, Saykally R. Raman thermometry measurements of free evaporation from liquid water droplets. J Am Chem Soc. 2006 Oct 4; 128(39):12892-8. PMID: 17002384.
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      50. Petersen PB, Saykally R. Comment on "Interfacial pH at an isolated silica-water surface". J Phys Chem B. 2006 Aug 3; 110(30):15037-8; discussion 15039-40. PMID: 16869619.
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      51. Petersen PB, Saykally R. Probing the interfacial structure of aqueous electrolytes with femtosecond second harmonic generation spectroscopy. J Phys Chem B. 2006 Jul 27; 110(29):14060-73. PMID: 16854101.
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      52. Miller AE, Fischer AJ, Laurence T, Hollars CW, Saykally R, Lagarias JC, Huser T. Single-molecule dynamics of phytochrome-bound fluorophores probed by fluorescence correlation spectroscopy. Proc Natl Acad Sci U S A. 2006 Jul 25; 103(30):11136-41. PMID: 16844775.
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      53. Lin W, Han JX, Takahashi LK, Loeser JG, Saykally R. Terahertz vibration-rotation-tunneling spectroscopy of the ammonia dimer: characterization of an out of plane vibration. J Phys Chem A. 2006 Jul 6; 110(26):8011-6. PMID: 16805485.
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      54. Bush MF, Saykally R, Williams ER. Formation of hydrated triply charged metal ions from aqueous solutions using nanodrop mass spectrometry. Int J Mass Spectrom. 2006 Jul 1; 253(3):256-262. PMID: 19081753.
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      55. Scribano Y, Goldman N, Saykally R, Leforestier C. Water dimers in the atmosphere III: equilibrium constant from a flexible potential. J Phys Chem A. 2006 Apr 27; 110(16):5411-9. PMID: 16623469.
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      56. Knutsen KP, Messer BM, Onorato RM, Saykally R. Chirped coherent anti-stokes Raman scattering for high spectral resolution spectroscopy and chemically selective imaging. J Phys Chem B. 2006 Mar 30; 110(12):5854-64. PMID: 16553391.
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      57. Cappa CD, Smith JD, Messer BM, Cohen RC, Saykally R. Effects of cations on the hydrogen bond network of liquid water: new results from X-ray absorption spectroscopy of liquid microjets. J Phys Chem B. 2006 Mar 23; 110(11):5301-9. PMID: 16539461.
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      58. Cappa CD, Smith JD, Messer BM, Cohen RC, Saykally R. The electronic structure of the hydrated proton: a comparative X-ray absorption study of aqueous HCl and NaCl solutions. J Phys Chem B. 2006 Jan 26; 110(3):1166-71. PMID: 16471659.
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      59. Petersen PB, Saykally R. On the nature of ions at the liquid water surface. Annu Rev Phys Chem. 2006; 57:333-64. PMID: 16599814.
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      60. Cappa CD, Drisdell WS, Smith JD, Saykally R, Cohen RC. Isotope fractionation of water during evaporation without condensation. J Phys Chem B. 2005 Dec 29; 109(51):24391-400. PMID: 16375440.
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      61. Messer BM, Cappa CD, Smith JD, Drisdell WS, Schwartz CP, Cohen RC, Saykally R. Local hydration environments of amino acids and dipeptides studied by X-ray spectroscopy of liquid microjets. J Phys Chem B. 2005 Nov 24; 109(46):21640-6. PMID: 16853810.
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      62. Petersen PB, Saykally R. Adsorption of ions to the surface of dilute electrolyte solutions: the Jones-Ray effect revisited. J Am Chem Soc. 2005 Nov 9; 127(44):15446-52. PMID: 16262408.
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      63. Smith JD, Cappa CD, Wilson KR, Cohen RC, Geissler PL, Saykally R. Unified description of temperature-dependent hydrogen-bond rearrangements in liquid water. Proc Natl Acad Sci U S A. 2005 Oct 4; 102(40):14171-4. PMID: 16179387.
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      64. Peng P, Milliron DJ, Hughes SM, Johnson JC, Alivisatos AP, Saykally R. Femtosecond spectroscopy of carrier relaxation dynamics in type II CdSe/CdTe tetrapod heteronanostructures. Nano Lett. 2005 Sep; 5(9):1809-13. PMID: 16159228.
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      65. Stephenson SK, Saykally R. Velocity modulation spectroscopy of ions. Chem Rev. 2005 Sep; 105(9):3220-34. PMID: 16159151.
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      66. Harker HA, Viant MR, Keutsch FN, Michael EA, McLaughlin RP, Saykally R. Water pentamer: characterization of the torsional-puckering manifold by terahertz VRT spectroscopy. J Phys Chem A. 2005 Jul 28; 109(29):6483-97. PMID: 16833993.
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      67. Petersen PB, Saykally R, Mucha M, Jungwirth P. Enhanced concentration of polarizable anions at the liquid water surface: SHG spectroscopy and MD simulations of sodium thiocyanate [corrected]. J Phys Chem B. 2005 Jun 2; 109(21):10915-21. PMID: 16852329.
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      68. Wilson KR, Cavalleri M, Rude BS, Schaller RD, Catalano T, Nilsson A, Saykally R, Pettersson LG. X-ray absorption spectroscopy of liquid methanol microjets: bulk electronic structure and hydrogen bonding network. J Phys Chem B. 2005 May 26; 109(20):10194-203. PMID: 16852236.
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      69. Sirbuly DJ, Law M, Pauzauskie P, Yan H, Maslov AV, Knutsen K, Ning CZ, Saykally R, Yang P. Optical routing and sensing with nanowire assemblies. Proc Natl Acad Sci U S A. 2005 May 31; 102(22):7800-5. PMID: 15911765.
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      70. Law M, Greene LE, Johnson JC, Saykally R, Yang P. Nanowire dye-sensitized solar cells. Nat Mater. 2005 Jun; 4(6):455-9. PMID: 15895100.
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      71. Petersen PB, Saykally R. Evidence for an enhanced hydronium concentration at the liquid water surface. J Phys Chem B. 2005 Apr 28; 109(16):7976-80. PMID: 16851932.
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      72. Cappa CD, Smith JD, Wilson KR, Messer BM, Gilles MK, Cohen RC, Saykally R. Effects of alkali metal halide salts on the hydrogen bond network of liquid water. J Phys Chem B. 2005 Apr 21; 109(15):7046-52. PMID: 16851801.
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      73. Messer BM, Cappa CD, Smith JD, Wilson KR, Gilles MK, Cohen RC, Saykally R. pH dependence of the electronic structure of glycine. J Phys Chem B. 2005 Mar 24; 109(11):5375-82. PMID: 16863204.
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      74. Goldman N, Leforestier C, Saykally R. A 'first principles' potential energy surface for liquid water from VRT spectroscopy of water clusters. Philos Trans A Math Phys Eng Sci. 2005 Feb 15; 363(1827):493-508. PMID: 15664895.
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      75. Smith JD, Cappa CD, Wilson KR, Messer BM, Cohen RC, Saykally R. Energetics of hydrogen bond network rearrangements in liquid water. Science. 2004 Oct 29; 306(5697):851-3. PMID: 15514152.
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      76. Law M, Sirbuly DJ, Johnson JC, Goldberger J, Saykally R, Yang P. Nanoribbon waveguides for subwavelength photonics integration. Science. 2004 Aug 27; 305(5688):1269-73. PMID: 15333835.
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      77. Haber LH, Schaller RD, Johnson JC, Saykally R. Shape control of near-field probes using dynamic meniscus etching. J Microsc. 2004 Apr; 214(Pt 1):27-35. PMID: 15049865.
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      78. Huneycutt AJ, Casaes RN, McCall BJ, Chung CY, Lee YP, Saykally R. Infrared cavity ringdown spectroscopy of jet-cooled polycyclic aromatic hydrocarbons. Chemphyschem. 2004 Mar 19; 5(3):321-6. PMID: 15067868.
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      79. Goldman N, Saykally R. Elucidating the role of many-body forces in liquid water. I. Simulations of water clusters on the VRT(ASP-W) potential surfaces. J Chem Phys. 2004 Mar 8; 120(10):4777-89. PMID: 15267338.
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      80. Schaller RD, Johnson JC, Saykally R. Time-resolved second harmonic generation near-field scanning optical microscopy. Chemphyschem. 2003 Nov 14; 4(11):1243-7. PMID: 14653007.
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      81. Schaller RD, Saykally R, Shen YR, Lagugné-Labarthet F. Poled polymer thin-film gratings studied with far-field optical diffraction and second-harmonic near-field microscopy. Opt Lett. 2003 Aug 1; 28(15):1296-8. PMID: 12906068.
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      82. Greene LE, Law M, Goldberger J, Kim F, Johnson JC, Zhang Y, Saykally R, Yang P. Low-temperature wafer-scale production of ZnO nanowire arrays. Angew Chem Int Ed Engl. 2003 Jul 7; 42(26):3031-4. PMID: 12851963.
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      83. Keutsch FN, Cruzan JD, Saykally R. The water trimer. Chem Rev. 2003 Jul; 103(7):2533-77. PMID: 12848579.
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      84. Yan H, He R, Johnson J, Law M, Saykally R, Yang P. Dendritic nanowire ultraviolet laser array. J Am Chem Soc. 2003 Apr 23; 125(16):4728-9. PMID: 12696889.
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      85. McCall BJ, Huneycutt AJ, Saykally R, Geballe TR, Djuric N, Dunn GH, Semaniak J, Novotny O, Al-Khalili A, Ehlerding A, Hellberg F, Kalhori S, Neau A, Thomas R, Osterdahl F, Larsson M. An enhanced cosmic-ray flux towards zeta Persei inferred from a laboratory study of the H3+-e- recombination rate. Nature. 2003 Apr 3; 422(6931):500-2. PMID: 12673244.
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      86. Huneycutt AJ, Saykally R. Chemistry. Building solutions--one molecule at a time. Science. 2003 Feb 28; 299(5611):1329-30. PMID: 12610288.
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      87. Lee LF, Adronov A, Schaller RD, Fréchet JM, Saykally R. Intermolecular coupling in nanometric domains of light-harvesting dendrimer films studied by photoluminescence near-field scanning optical microscopy (PL NSOM). J Am Chem Soc. 2003 Jan 15; 125(2):536-40. PMID: 12517168.
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      88. Johnson JC, Choi HJ, Knutsen KP, Schaller RD, Yang P, Saykally R. Single gallium nitride nanowire lasers. Nat Mater. 2002 Oct; 1(2):106-10. PMID: 12618824.
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      89. Kraus D, Saykally R, Bondybey VE. Cavity-ringdown spectroscopy studies of the B2 sigma+<--X2 sigma+ Rsystem of AIO. Chemphyschem. 2002 Apr 15; 3(4):364-6. PMID: 12465517.
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      90. Lee LF, Schaller RD, Haber LH, Saykally R. High spatial resolution imaging with near-field scanning optical microscopy in liquids. Anal Chem. 2001 Nov 1; 73(21):5015-9. PMID: 11721893.
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      91. Keutsch FN, Saykally R. Water clusters: untangling the mysteries of the liquid, one molecule at a time. Proc Natl Acad Sci U S A. 2001 Sep 11; 98(19):10533-40. PMID: 11535820.
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      92. Keutsch FN, Fellers RS, Brown MG, Viant MR, Petersen PB, Saykally R. Hydrogen bond breaking dynamics of the water trimer in the translational and librational band region of liquid water. J Am Chem Soc. 2001 Jun 27; 123(25):5938-41. PMID: 11414826.
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      93. Kim HS, Wagner DR, Saykally R. Single photon infrared emission spectroscopy of the gas phase pyrene cation: support for a polycyclic aromatic hydrocarbon origin of the unidentified infrared emission bands. Phys Rev Lett. 2001 Jun 18; 86(25):5691-4. PMID: 11415334.
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      94. Giesen TF, Berndt U, Yamada KM, Fuchs G, Schieder R, Winnewisser G, Provencal RA, Keutsch FN, Van Orden A, Saykally R. Detection of the linear carbon cluster C10: rotationally resolved diode-laser spectroscopy. Chemphyschem. 2001 Apr 17; 2(4):242-7. PMID: 23696487.
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      95. Keutsch FN, Goldman N, Karyakin EN, Harker HA, Sanz ME, Leforestier C, Saykally R. Complete characterization of the (D2O)2 ground state: high Ka rotation-tunneling levels. Faraday Discuss. 2001; (118):79-93; discussion 109-19. PMID: 11605283.
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      96. Wagner DR, Kim HS, Saykally R. Peripherally hydrogenated neutral polycyclic aromatic hydrocarbons as carriers of the 3 micron interstellar infrared emission complex: results from single-photon infrared emission spectroscopy. Astrophys J. 2000 Dec 20; 545(2 Pt 1):854-60. PMID: 11878349.
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      97. Schaller RD, Johnson JC, Saykally R. Nonlinear chemical imaging microscopy: near-field third harmonic generation imaging of human red blood cells. Anal Chem. 2000 Nov 1; 72(21):5361-4. PMID: 11080888.
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      98. Fellers RS, Leforestier C, Braly LB, Brown MG, Saykally R. Spectroscopic determination of the water pair potential. Science. 1999 May 7; 284(5416):945-8. PMID: 10320371.
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      99. Van Orden A, Saykally R. Small carbon clusters: spectroscopy, structure, and energetics. Chem Rev. 1998 Sep-Oct; 98(6):2313-57. PMID: 11543299.
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      100. Provencal RA, Paul JB, Michael E, Saykally R. Absorption spectroscopy: technique provides extremely high sensitivity. Photonics Spectra. 1998 Jun; 32(6):159-66. PMID: 11541906.
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      101. Cook DJ, Schlemmer S, Balucani N, Wagner DR, Harrison JA, Steiner B, Saykally R. Single photon infrared emission spectroscopy: a study of IR emission from UV laser excited PAHs between 3 and 15 micrometers. J Phys Chem A. 1998 Feb 26; 102(9):1465-81. PMID: 11542815.
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      102. Cook DJ, Saykally R. Simulated infrared emission spectra of highly excited polyatomic molecules: a detailed model of the PAH-UIR hypothesis. Astrophys J. 1998 Feb 1; 493 Pt 1(2):793-802. PMID: 11541733.
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      103. Scherer JJ, Paul JB, O'Keefe A, Saykally R. Cavity Ringdown Laser Absorption Spectroscopy: History, Development, and Application to Pulsed Molecular Beams. Chem Rev. 1997 Feb 05; 97(1):25-52. PMID: 11848864.
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      104. Liu K, Brown MG, Viant MR, Cruzan JD, Saykally R. Far-infrared VRT spectroscopy of two water trimer isotopomers: vibrationally averaged structures and rearrangement dynamics. Mol Phys. 1996 Dec 10; 89(5):1373-96. PMID: 11539422.
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      105. Heath JR, Saykally R. Space carbon: neutral pathways? Science. 1996 Nov 29; 274(5292):1480-1. PMID: 8966618.
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      106. Van Orden A, Provencal RA, Keutsch FN, Saykally R. Infrared laser spectroscopy of jet-cooled carbon clusters: the nu 5 band of linear C9. J Chem Phys. 1996 Oct 15; 105(15):6111-6. PMID: 11541745.
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      107. Cook DJ, Schlemmer S, Balucani N, Wagner DR, Steiner B, Saykally R. Infrared emission spectra of candidate interstellar aromatic molecules. Nature. 1996 Mar 21; 380(6571):227-9. PMID: 8637570.
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      108. Paul JB, Scherer JJ, Collier CP, Saykally R. Cavity ringdown laser absorption spectroscopy and time-of-flight mass spectroscopy of jet cooled platinum silicides. J Chem Phys. 1996 Feb 22; 104(8):2782-8. PMID: 11539202.
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      109. Cruzan JD, Braly LB, Liu K, Brown MG, Loeser JG, Saykally R. Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer. Science. 1996 Jan 5; 271(5245):59-62. PMID: 11536731.
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      110. Elrod MJ, Saykally R. Vibration--rotation--tunneling dynamics calculations for the four-dimensional (HCl)2 system: a test of approximate models. J Chem Phys. 1995 Jul 15; 103(3):921-32. PMID: 11539396.
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      111. Elrod MJ, Saykally R. Determination of the intermolecular potential energy surface for (HCl)2 from vibration--rotation--tunneling spectra. J Chem Phys. 1995 Jul 15; 103(3):933-49. PMID: 11539397.
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      112. Van Orden A, Provencal RA, Giesen TF, Saykally R. Characterization of silicon-carbon clusters by infrared laser spectroscopy. The nu 1 band of SiC4. Chem Phys Lett. 1995 May 5; 237:77-80. PMID: 11539829.
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      113. Heath JR, Van Orden A, Hwang HJ, Kuo EW, Tanaka K, Saykally R. Toward the detection of pure carbon clusters in the ISM. Adv Space Res. 1995 Mar; 15(3):25-33. PMID: 11539233.
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      114. Van Orden A, Giesen TF, Provencal RA, Hwang HJ, Saykally R. Characterization of silicon-carbon clusters by infrared laser spectroscopy: the nu 3(sigma u) band of linear Si2C3. J Chem Phys. 1994 Dec 15; 101(12):10237-41. PMID: 11539561.
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      115. Elrod MJ, Saykally R. Many-body effects in intermolecular forces. Chem Rev. 1994 Nov; 94(7):1975-97. PMID: 11539597.
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      116. Schlemmer S, Cook DJ, Harrison JA, Wurfel B, Chapman W, Saykally R. The unidentified interstellar infrared bands: PAHs as carriers? Science. 1994 Sep 16; 265:1686-9. PMID: 11539830.
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      117. van der Sanden GC, Wormer PE, van der Avoird A, Schmuttenmaer CA, Saykally R. Close coupling results for inelastic collisions of NH3 and Ar. A stringent test of a spectroscopic potential. Chem Phys Lett. 1994 Aug 12; 226(1-2):22-6. PMID: 11539419.
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      118. Giesen TF, Van Orden A, Hwang HJ, Fellers RS, Provencal RA, Saykally R. Infrared laser spectroscopy of the linear C13 carbon cluster. Science. 1994 Aug 5; 265:756-9. PMID: 11539187.
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      119. Van Orden A, Hwang HJ, Kuo EW, Saykally R. Infrared laser spectroscopy of jet-cooled carbon clusters: the bending dynamics of linear C9. J Chem Phys. 1993 May 1; 98(9):6678-83. PMID: 11538714.
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      120. Saykally R, Blake GA. Molecular interactions and hydrogen bond tunneling dynamics: some new perspectives. Science. 1993 Mar 12; 259(5101):1570-5. PMID: 17733020.
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      121. Hwang HJ, Van Orden A, Tanaka K, Kuo EW, Heath JR, Saykally R. Infrared laser spectroscopy of jet-cooled carbon clusters: structure of triplet C6. Mol Phys. 1993; 79(4):769-76. PMID: 11539837.
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      122. Pugliano N, Saykally R. Measurement of quantum tunneling between chiral isomers of the cyclic water trimer. Science. 1992 Sep 25; 257(5078):1937-40. PMID: 1411509.
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      123. Heath JR, Saykally R. The C9 cluster: structure and infrared frequencies. J Chem Phys. 1990 Dec 1; 93(11):8392-4. PMID: 11538485.
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      124. Heath JR, Sheeks RA, Cooksy AL, Saykally R. The C7 cluster: structure and infrared frequencies. Science. 1990 Aug 24; 249:895-7. PMID: 11538081.
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      125. Schmuttenmaer CA, Cohen RC, Pugliano N, Heath JR, Cooksy AL, Busarow KL, Saykally R. Tunable far-IR laser spectroscopy of jet-cooled carbon clusters: the nu 2 bending vibration of C3. Science. 1990 Aug 24; 249:897-900. PMID: 11538082.
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      126. Hawkins JM, Lewis TA, Loren SD, Meyer A, Heath JR, Shibato Y, Saykally R. Organic chemistry of C60 (Buckminsterfullerene): chromatography and osmylation. J Org Chem. 1990; 55(26):6250-2. PMID: 11540923.
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      127. Heath JR, Cooksy AL, Gruebele MH, Schmuttenmaer CA, Saykally R. Diode-laser absorption spectroscopy of supersonic carbon cluster beams: the nu 3 spectrum of C5. Science. 1989 May 5; 244:564-6. PMID: 11539817.
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      128. Saykally R. Infrared laser spectroscopy of molecular ions. Science. 1988 Jan 8; 239(4836):157-61. PMID: 17732977.
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      129. Gudeman CS, Begemann MH, Pfaff J, Saykally R. Tone-burst modulated color-center-laser spectroscopy. Opt Lett. 1983 Jun 1; 8(6):310-2. PMID: 19718097.
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