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    Frei, Heinz

    TitleChemist Sr Staff Sci/Engr
    SchoolLawrence Berkeley National Lab
    DepartmentMolecular Biophys & Integ Bio
    Address1 Cyclotron Road
    Berkeley CA 94720
    Phone510/486-4325
    vCardDownload vCard

      Collapse Bibliographic 
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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Zhang M, Frei H. Water Oxidation Mechanisms of Metal Oxide Catalysts by Vibrational Spectroscopy of Transient Intermediates. Annu Rev Phys Chem. 2017 Feb 22. PMID: 28226220.
        View in: PubMed
      2. Kisielowski C, Frei H, Specht P, Sharp ID, Haber JA, Helveg S. Detecting structural variances of Co3O4 catalysts by controlling beam-induced sample alterations in the vacuum of a transmission electron microscope. Adv Struct Chem Imaging. 2017; 2(1):13. PMID: 27867836.
        View in: PubMed
      3. Alonso-Mori R, Asa K, Bergmann U, Brewster AS, Chatterjee R, Cooper JK, Frei H, Fuller FD, Goggins E, Gul S, Fukuzawa H, Iablonskyi D, Ibrahim M, Katayama T, Kroll T, Kumagai Y, McClure BA, Messinger J, Motomura K, Nagaya K, Nishiyama T, Saracini C, Sato Y, Sauter NK, Sokaras D, Takanashi T, Togashi T, Ueda K, Weare WW, Weng TC, Yabashi M, Yachandra VK, Young ID, Zouni A, Kern JF, Yano J. Towards characterization of photo-excited electron transfer and catalysis in natural and artificial systems using XFELs. Faraday Discuss. 2016 Sep 14. PMID: 27711803.
        View in: PubMed
      4. Kim W, Edri E, Frei H. Hierarchical Inorganic Assemblies for Artificial Photosynthesis. Acc Chem Res. 2016 Sep 20; 49(9):1634-45. PMID: 27575376.
        View in: PubMed
      5. Sheng H, Frei H. Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraaza Catalyst [Co(II)N4H(MeCN)](2+) Converting CO2 to CO. J Am Chem Soc. 2016 Aug 10; 138(31):9959-67. PMID: 27420191.
        View in: PubMed
      6. Kim W, McClure BA, Edri E, Frei H. Coupling carbon dioxide reduction with water oxidation in nanoscale photocatalytic assemblies. Chem Soc Rev. 2016 Jun 7; 45(11):3221-43. PMID: 27121982.
        View in: PubMed
      7. Maier J, Liu P, Hu X, Stucky G, Sun SG, Chen L, Han W, Whang DR, Chen G, Zhan C, He J, Cronin L, Yang S, Reisner E, Long L, Mount A, Seshadri R, Yang X, Pan F, Liu H, Li Z, Tian Z, Frei H, Luo J, Li F, Du P, Wang B, Li Y, Zhao Y, Sun L, Hisatomi T, Li C, Zhu K, Park NG, Wang H, Gr├Ątzel M. Solar cells and photocatalytic systems: general discussion. Faraday Discuss. 2014; 176:313-31. PMID: 25697567.
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      8. Mount A, Xiong S, Shan X, Lee HW, Yu X, Chao Y, Stucky G, Chen G, Qi Z, Hutchings G, Zhong Y, Holze R, Han W, Cronin L, Yang S, Li H, Hong X, Reisner E, Yang Y, Xuan W, Grey C, Seshadri R, Mai L, Xie J, Pan F, Li Z, Maier J, Tian Z, Chen Y, Mao B, Frei H, Lin C, Liao F, Liu D, Zheng N, Lin R, Vannier RN, Deng D, M Griffin J, Markovic N, Zheng H, Kanno R. Electrochemical conversion and storage systems: general discussion. Faraday Discuss. 2014; 176:153-84. PMID: 25699523.
        View in: PubMed
      9. Yuan G, Agiral A, Pellet N, Kim W, Frei H. Inorganic core-shell assemblies for closing the artificial photosynthetic cycle. Faraday Discuss. 2015; 176:233-49. PMID: 25430968.
        View in: PubMed
      10. Kim W, Yuan G, McClure BA, Frei H. Light Induced Carbon Dioxide Reduction by Water at Binuclear ZrOCo(II) Unit Coupled to Ir Oxide Nanocluster Catalyst. J Am Chem Soc. 2014 Aug 6; 136(31):11034-42. PMID: 25033315.
        View in: PubMed
      11. Yang J, Walczak K, Anzenberg E, Toma FM, Yuan G, Beeman J, Schwartzberg A, Lin Y, Hettick M, Javey A, Ager JW, Yano J, Frei H, Sharp ID. Efficient and sustained photoelectrochemical water oxidation by cobalt oxide/silicon photoanodes with nanotextured interfaces. J Am Chem Soc. 2014 Apr 30; 136(17):6191-4. PMID: 24720554.
        View in: PubMed
      12. Shu XZ, Zhang M, He Y, Frei H, Toste FD. Dual visible light photoredox and gold-catalyzed arylative ring expansion. J Am Chem Soc. 2014 Apr 23; 136(16):5844-7. PMID: 24730447.
        View in: PubMed
      13. Zhang M, de Respinis M, Frei H. Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst. Nat Chem. 2014 Apr; 6(4):362-7. PMID: 24651205.
        View in: PubMed
      14. Soo HS, Agiral A, Bachmeier A, Frei H. Visible light-induced hole injection into rectifying molecular wires anchored on Co3O4 and SiO2 nanoparticles. J Am Chem Soc. 2012 Oct 17; 134(41):17104-16. PMID: 22934720.
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      15. Sivasankar N, Weare WW, Frei H. Direct observation of a hydroperoxide surface intermediate upon visible light-driven water oxidation at an Ir oxide nanocluster catalyst by rapid-scan FT-IR spectroscopy. J Am Chem Soc. 2011 Aug 24; 133(33):12976-9. PMID: 21770440.
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      16. Jiao F, Frei H. Nanostructured manganese oxide clusters supported on mesoporous silica as efficient oxygen-evolving catalysts. Chem Commun (Camb). 2010 May 7; 46(17):2920-2. PMID: 20386823.
        View in: PubMed
      17. Somorjai GA, Frei H, Park JY. Advancing the frontiers in nanocatalysis, biointerfaces, and renewable energy conversion by innovations of surface techniques. J Am Chem Soc. 2009 Nov 25; 131(46):16589-605. PMID: 19919130.
        View in: PubMed
      18. Wu X, Weare WW, Frei H. Binuclear TiOMn charge-transfer chromophore in mesoporous silica. Dalton Trans. 2009 Dec 7; (45):10114-21. PMID: 19904439.
        View in: PubMed
      19. Borodko Y, Jones L, Lee H, Frei H, Somorjai G. Spectroscopic study of tetradecyltrimethylammonium bromide Pt-C14TAB nanoparticles: structure and stability. Langmuir. 2009 Jun 16; 25(12):6665-71. PMID: 19397251.
        View in: PubMed
      20. Jiao F, Frei H. Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. Angew Chem Int Ed Engl. 2009; 48(10):1841-4. PMID: 19173364.
        View in: PubMed
      21. Weare WW, Pushkar Y, Yachandra VK, Frei H. Visible light-induced electron transfer from di-mu-oxo-bridged dinuclear Mn complexes to Cr centers in silica nanopores. J Am Chem Soc. 2008 Aug 27; 130(34):11355-63. PMID: 18665599.
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      22. Mul G, Wasylenko W, Hamdy MS, Frei H. Cyclohexene photo-oxidation over vanadia catalyst analyzed by time resolved ATR-FT-IR spectroscopy. Phys Chem Chem Phys. 2008 Jun 7; 10(21):3131-7. PMID: 18688378.
        View in: PubMed
      23. Wasylenko W, Frei H. Direct observation of the kinetically relevant site of CO hydrogenation on supported Ru catalyst at 700 K by time-resolved FT-IR spectroscopy. Phys Chem Chem Phys. 2007 Oct 28; 9(40):5497-502. PMID: 17925976.
        View in: PubMed
      24. Borodko Y, Habas SE, Koebel M, Yang P, Frei H, Somorjai GA. Probing the interaction of poly(vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR. J Phys Chem B. 2006 Nov 23; 110(46):23052-9. PMID: 17107143.
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      25. Andersen LK, Frei H. Dynamics of CO in mesoporous silica monitored by time-resolved step-scan and rapid-scan FT-IR spectroscopy. J Phys Chem B. 2006 Nov 16; 110(45):22601-7. PMID: 17092007.
        View in: PubMed
      26. Nakamura R, Frei H. Visible light-driven water oxidation by Ir oxide clusters coupled to single Cr centers in mesoporous silica. J Am Chem Soc. 2006 Aug 23; 128(33):10668-9. PMID: 16910647.
        View in: PubMed
      27. Frei H. Chemistry. Selective hydrocarbon oxidation in zeolites. Science. 2006 Jul 21; 313(5785):309-10. PMID: 16857928.
        View in: PubMed
      28. Cahoon JF, Kling MF, Sawyer KR, Frei H, Harris CB. 19-electron intermediates in the ligand substitution of CpW(CO)3* with a Lewis base. J Am Chem Soc. 2006 Mar 15; 128(10):3152-3. PMID: 16522089.
        View in: PubMed
      29. Wasylenko W, Frei H. Direct observation of surface ethyl to ethane interconversion upon C2H4 hydrogenation over Pt/Al2O3 catalyst by time-resolved FT-IR spectroscopy. J Phys Chem B. 2005 Sep 8; 109(35):16873-8. PMID: 16853147.
        View in: PubMed
      30. Lin W, Frei H. Anchored metal-to-metal charge-transfer chromophores in a mesoporous silicate sieve for visible-light activation of titanium centers. J Phys Chem B. 2005 Mar 24; 109(11):4929-35. PMID: 16863149.
        View in: PubMed
      31. Lin W, Frei H. Photochemical CO2 splitting by metal-to-metal charge-transfer excitation in mesoporous ZrCu(I)-MCM-41 silicate sieve. J Am Chem Soc. 2005 Feb 16; 127(6):1610-1. PMID: 15700974.
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      32. Asplund MC, Snee PT, Yeston JS, Wilkens MJ, Payne CK, Yang H, Kotz KT, Frei H, Bergman RG, Harris CB. Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. J Am Chem Soc. 2002 Sep 4; 124(35):10605-12. PMID: 12197763.
        View in: PubMed
      33. Lin W, Frei H. Photochemical and FT-IR probing of the active site of hydrogen peroxide in Ti silicalite sieve. J Am Chem Soc. 2002 Aug 7; 124(31):9292-8. PMID: 12149037.
        View in: PubMed

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